Counterion phase transitions in dilute polyelectrolyte solutions

被引:99
作者
Deshkovski, A
Obukhov, S
Rubinstein, M
机构
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
[2] Univ Florida, Dept Phys, Gainesville, FL 32611 USA
关键词
D O I
10.1103/PhysRevLett.86.2341
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
In dilute solutions of rodlike polyelectrolytes some counterions are distributed far from polyions while others are located in their vicinity in the regions of cylindrical symmetry of the electrostatic potential. For these cylindrical regions around rodlike polyelectrolytes we find an exact solution of the nonlinear Poisson-Boltzmann equation for the case of nonzero net charge in these regions. This exact solution implies three qualitatively different phases of counterion distribution around the polyions with Second order phase transitions between these phases.
引用
收藏
页码:2341 / 2344
页数:4
相关论文
共 18 条
[1]   THE COUNTERION DISTRIBUTION IN SOLUTIONS OF ROD-SHAPED POLYELECTROLYTES [J].
ALFREY, T ;
BERG, PW ;
MORAWETZ, H .
JOURNAL OF POLYMER SCIENCE, 1951, 7 (05) :543-547
[2]  
Barrat JL, 1996, ADV CHEM PHYS, V94, P1, DOI 10.1002/9780470141533.ch1
[3]   Fraction of condensed counterions around a charged rod: Comparison of Poisson-Boltzmann theory and computer simulations [J].
Deserno, M ;
Holm, C ;
May, S .
MACROMOLECULES, 2000, 33 (01) :199-206
[4]   THE POTENTIAL OF AN INFINITE ROD-LIKE MOLECULE AND THE DISTRIBUTION OF THE COUNTER IONS [J].
FUOSS, RM ;
KATCHALSKY, A ;
LIFSON, S .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1951, 37 (09) :579-589
[5]  
LEBRET M, 1984, BIOPOLYMERS, V23, P287
[6]  
LEE N, UNPUB
[7]   THE ELECTROSTATIC FREE ENERGY OF POLYELECTROLYTE SOLUTIONS .2. FULLY STRETCHED MACROMOLECULES [J].
LIFSON, S ;
KATCHALSKY, A .
JOURNAL OF POLYMER SCIENCE, 1954, 13 (68) :43-55
[8]   LIMITING LAWS AND COUNTERION CONDENSATION IN POLYELECTROLYTE SOLUTIONS .3. AN ANALYSIS BASED ON MAYER IONIC SOLUTION THEORY [J].
MANNING, GS .
JOURNAL OF CHEMICAL PHYSICS, 1969, 51 (08) :3249-&
[9]   The critical onset of counterion condensation: A survey of its experimental and theoretical basis [J].
Manning, GS .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1996, 100 (06) :909-922