Ru complexes bearing bidentate carbenes: from innocent curiosity to uniquely effective catalysts for olefin metathesis

被引：319

作者：

Hoveyda, AH ^{[1
]}

Gillingham, DG ^{[1
]}

Van Veldhuizen, JJ ^{[1
]}

Kataoka, O ^{[1
]}

Garber, SB ^{[1
]}

Kingsbury, JS ^{[1
]}

Harrity, JPA ^{[1
]}

机构：

[1] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02467 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2004年 / 2卷 / 01期

关键词：

D O I：

10.1039/b311496c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The discovery and development of a new class of Ru-based catalysts for olefin metathesis is described. These catalysts, particularly those that do not bear a phosphine ligand, have been demonstrated to promote unique levels of reactivity in a variety of olefin metathesis reactions. The design and development of supported and chiral optically pure variants of this class of Ru catalysts for use in enantioselective metathesis are discussed as well. All catalysts are air stable, reusable, and can be employed with unpurified solvents.

引用

页码：8 / 23

页数：16

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