A Planar {Mn19(OH)12}26+ Unit Incorporated in a 60-Tungsto-6-Silicate Polyanion

被引：177

作者：

Bassil, Bassem S. ^{[1
]}

Ibrahim, Masooma ^{[1
]}

Al-Oweini, Rami ^{[1
]}

Asano, Marie ^{[1
]}

Wang, Zhenxing ^{[2
]}

van Tol, Johan ^{[2
]}

Dalal, Naresh S. ^{[2
]}

Choi, Kwang-Yong ^{[3
]}

Rosa Ngo Biboum ^{[4
]}

Keita, Bineta ^{[4
]}

Nadjo, Louis ^{[4
]}

Kortz, Ulrich ^{[1
]}

机构：

[1] Jacobs Univ, Sch Sci & Engn, D-28725 Bremen, Germany

[2] Florida State Univ, Natl High Magnet Field Lab, Dept Chem & Biochem, Tallahassee, FL 32306 USA

[3] Chung Ang Univ, Dept Phys, Seoul 156756, South Korea

[4] Univ Paris 11, Lab Chim Phys, F-91405 Orsay, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 26期

关键词：

electrochemistry; magnetic properties; manganese; polyoxometalates; structure elucidation; SINGLE-MOLECULE MAGNET; BUILDING-BLOCKS; CLUSTERS; WHEEL; COMPLEXES; AGGREGATE; PHOSPHATE; CATALYST; WATER; ION;

D O I：

10.1002/anie.201007617

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Manganese in large numbers: The largest number of manganese ions ever incorporated in a polyoxometalate (POM) is found in a planar Mn 19-oxo-hydroxo magnetic cluster incorporated in a discrete 60-tungsto-6-silicate (see structure Mn yellow, O red/pink). The compound has interesting structural, magnetic, and electrochemical properties. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5961 / 5964

页数：4

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