Use and recovery of a homogeneous catalyst with carbon dioxide as a solubility switch

被引：35

作者：

Ablan, CD

Hallett, JP

West, KN

Jones, RS

Eckert, CA

Liotta, CL

Jessop, PG

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

[2] Georgia Inst Technol, Sch Chem, Atlanta, GA 30332 USA

[3] Georgia Inst Technol, Sch Chem Engn, Atlanta, GA 30332 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 24期

关键词：

D O I：

10.1039/b311146f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A method for fluorous biphasic catalysis is described, in which the fluorous liquid is replaced by fluorinated silica, the fluorous catalyst is induced to dissolve in the organic solvent by the presence Of CO2, and the recovery of the catalyst after the reaction is achieved by release of the CO2 pressure.

引用

收藏

页码：2972 / 2973

页数：2

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