ORMOCER®s for optical interconnection technology

被引:173
作者
Buestrich, R [1 ]
Kahlenberg, F
Popall, M
Dannberg, P
Müller-Fiedler, R
Rösch, O
机构
[1] Fraunhofer Inst Silicatforsch, Wurzburg, Germany
[2] Fraunhofer Inst Angew Opt & Feinmech, Jena, Germany
[3] Robert Bosch GmbH, FV FLD, Stuttgart, Germany
关键词
ORMOCER; NIR; polysiloxane; waveguide; digital optical switch; integrated optics; inorganic-organic hybrid polymer;
D O I
10.1023/A:1008755607488
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
New inorganic-organic hybrid polymers (ORMOCER (R)s) for integrated optical and opto-electronic devices were synthesized by sol-gel processing of functionalized alkoxysilanes. Process parameters (catalyst, temperature etc.) were optimized to achieve highly reproducible low cost materials which are photopatternable even in higher layer thickness (presently 100 mum within one step). The resulting materials have low optical losses at the most important wavelengths for telecommunications in the NIR range (0.3 dB/cm at 1320 nm, 0.6 dB/cm at 1550 nm) and a variety of additional advantageous properties for optical interconnection technology and production of opto-electronic devices: good wetting and adhesion on various substrates (e.g. glass, silicon and several polymers), low processing temperatures (post-bake at 150 degreesC) and high thermal stability (decomposition at 270 degreesC) compared to alternative opto-polymers for NIR applications. A further advantage is a tunable refractive index, which can be achieved by mixing different resins.
引用
收藏
页码:181 / 186
页数:6
相关论文
共 17 条
[1]  
[Anonymous], ANGEW CHEM
[2]  
BELLCORE, 1996, GENERIC REQUIREMENTS
[3]   Polymerization reactions in methyltriethoxysilane studied through 29Si NMR with polarization transfer [J].
Brunet, F .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 231 (1-2) :58-77
[4]   MODE CONVERSION IN PLANAR-DIELECTRIC SEPARATING WAVEGUIDES [J].
BURNS, WK ;
MILTON, AF .
IEEE JOURNAL OF QUANTUM ELECTRONICS, 1975, QE11 (01) :32-39
[5]   Sol-gel waveguide fabrication parameters: an experimental investigation [J].
Du, XM ;
Touam, T ;
Degachi, L ;
Guilbault, JL ;
Andrews, MP ;
Najafi, SI .
OPTICAL ENGINEERING, 1998, 37 (04) :1101-1104
[6]   Si-29 NMR investigation of condensation reactions of diphenylsilanediol in presence of Ti-, Zr-, Al-, Sn- and Si-alkoxides [J].
Hoebbel, D ;
Reinert, T ;
Schmidt, H .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1996, 7 (03) :217-224
[7]   LOW-LOSS, HEAT-RESISTANT OPTICAL WAVE-GUIDES USING NEW FLUORINATED POLYIMIDES [J].
MATSUURA, T ;
ANDO, S ;
SASAKI, S ;
YAMAMOTO, F .
ELECTRONICS LETTERS, 1993, 29 (03) :269-271
[8]   Sol-gel glass waveguide and grating on silicon [J].
Najafi, SI ;
Touam, T ;
Sara, R ;
Andrews, MP ;
Fardad, MA .
JOURNAL OF LIGHTWAVE TECHNOLOGY, 1998, 16 (09) :1640-1646
[9]  
Popall M, 1998, ELEC COMP C, P1018, DOI 10.1109/ECTC.1998.678838
[10]  
RANKIN S, 1998, CHEM MATER, V44, P1143