Cyclic dimer of a fused porphyrin zinc complex as a novel host with two π-electronically coupled binding sites

被引：36

作者：

Sato, H

Tashiro, K

Shinmori, H

Osuka, A

Aida, T

机构：

[1] Univ Tokyo, Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

[2] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 18期

关键词：

D O I：

10.1039/b501689d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon complexation with 4,4'-bipyridine, a cyclic dimer of a fused porphyrin zinc complex, having two pi-electronically coupled binding sites, shows a strong negative cooperativity in the second guest binding, to allow stepwise formation of 1 : 1 and 1 : 2 inclusion complexes.

引用

页码：2324 / 2326

页数：3

共 8 条

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