Influence of solvent structural variations on the mechanism of facilitated ion transfer into room-temperature ionic liquids

被引：252

作者：

Dietz, ML ^{[1
]}

Dzielawa, JA ^{[1
]}

Laszak, I ^{[1
]}

Young, BA ^{[1
]}

Jensen, MP ^{[1
]}

机构：

[1] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

来源：

GREEN CHEMISTRY | 2003年 / 5卷 / 06期

关键词：

D O I：

10.1039/b310507p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The predominant mode of strontium ion transfer from acidic nitrate media into a series of 1- alkyl- 3- methylimidazolium- based room- temperature ionic liquids containing dicyclohexano- 18- crown- 6 ( DCH18C6) shifts from cation exchange to strontium nitrato- crown ether complex partitioning as the hydrophobicity of the ionic liquid cation is increased.

引用

页码：682 / 685

页数：4

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