Solvolysis of β,β-dialkylvinyliodonium salt:: Primary vinyl cation intermediate and alkyl participation

被引：16

作者：

Okuyama, T ^{[1
]}

Sato, K

Ochiai, M

机构：

[1] Osaka Univ, Sch Engn Sci, Toyonaka, Osaka 5608531, Japan

[2] Univ Tokushima, Fac Pharmaceut Sci, Tokushima 7708505, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 11期

关键词：

D O I：

10.1246/cl.1998.1177

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvolysis of both E and Z isomers of a beta,beta-dialkylvinyl(phenyl)iodonium salt gave extensively rearranged products. A mechanism involving a primary vinyl cation intermediate as well as the alkyl participation leading to secondary vinyl cations is proposed.

引用

页码：1177 / 1178

页数：2

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