Short-time wave-packet dynamics and the reflection principle of continuum resonance Raman scattering

被引：9

作者：

Eichelsdorfer, M

Engel, V

机构：

[1] Inst. für Physikalische Chemie, Universität Würzburg, 97070 Würzburg

来源：

CHEMICAL PHYSICS LETTERS | 1996年 / 263卷 / 05期

关键词：

D O I：

10.1016/S0009-2614(96)01271-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We use the time-dependent approach to calculate cross sections for continuum resonance Raman scattering to derive the Raman reflection principle. The essential step in the derivation is to use a short-time approximation to the quantum mechanical propagators. Raman scattering from a diatomic molecule serves as an example to compare our approximate treatment with numerically exact results and a comparable formula derived by Lee [Chem. Phys. Lett. 203 (1993) 93].

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收藏

页码：640 / 644

页数：5

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