Enhancement of photocatalytic H2 evolution on CdS by loading MOS2 as cocatalyst under visible light irradiation

被引：1736

作者：

Zong, Xu ^{[1
]}

Yan, Hongjian ^{[1
]}

Wu, Guopeng ^{[1
]}

Ma, Guijun ^{[1
]}

Wen, Fuyu ^{[1
]}

Wang, Lu ^{[1
]}

Li, Can ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 23期

关键词：

D O I：

10.1021/ja8007825

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This communication presents our recent results that the activity of photocatalytic H-2 production can be significantly enhanced when a small amount of MoS2 is loaded on CdS as cocatalyst. The MoS2/CdS catalysts show high rate of H-2 evolution from photocatalytic re-forming of lactic acid under visible light irradiation. The rate of H-2 evolution on CdS is increased by up to 36 times when loaded with only 0.2 wt % of MoS2, and the activity of MoS2/CdS is even higher than those of the CdS photocatalysts loaded with different noble metals, such as Pt, Ru, Rh, Pd, and Au. The junction formed between MoS2 and CdS and the excellent H-2 activation property of MoS2 are supposed to be responsible for the enhanced photocatalytic activity of MoS2/CdS.

引用

页码：7176 / +

页数：3

共 32 条

[1] The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation
Anpo, M
Takeuchi, M
[J]. JOURNAL OF CATALYSIS, 2003, 216 (1-2) : 505 - 516
[2] BARD AJ, 1995, ACCOUNTS CHEM RES, V28, P91, DOI 10.1021/ar00051a001
[3] Catalytic properties of single layers of transition metal sulfide catalytic materials
Chianelli, Russell R.
Siadati, Mohammad H.
De la Rosa, Myriam Perez
Berhault, Gilles
Wilcoxon, Jess P.
Bearden, Roby, Jr.
Abrams, Billie L.
[J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2006, 48 (01): : 1 - 41
[4] The photocatalytic reforming of methanol
Dickinson, A
James, D
Perkins, N
Cassidy, T
Bowker, M
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 146 (1-2) : 211 - 221
[5] On the flexibility of the active phase in hydrotreating catalysts
Eijsbouts, S
[J]. APPLIED CATALYSIS A-GENERAL, 1997, 158 (1-2) : 53 - 92
[6] Unusual enhancement of H2 evolution by Ru on TaON photocatalyst under visible light irradiation
Hara, M
Nunoshige, J
Takata, T
Kondo, JN
Domen, K
[J]. CHEMICAL COMMUNICATIONS, 2003, (24) : 3000 - 3001
[7] Biornimetic hydrogen evolution:: MoS2 nanoparticles as catalyst for hydrogen evolution
Hinnemann, B
Moses, PG
Bonde, J
Jorgensen, KP
Nielsen, JH
Horch, S
Chorkendorff, I
Norskov, JK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (15) : 5308 - 5309
[8] An oxynitride, TaON, as an efficient water oxidation photocatalyst under visible light irradiation (λ ≤ 500 nm)
Hitoki, G
Takata, T
Kondo, JN
Hara, M
Kobayashi, H
Domen, K
[J]. CHEMICAL COMMUNICATIONS, 2002, (16) : 1698 - 1699
[9] Preparation and photocatalytic behavior of MoS2 and WS2 nanocluster sensitized TiO2
Ho, WK
Yu, JC
Lin, J
Yu, JG
Li, PS
[J]. LANGMUIR, 2004, 20 (14) : 5865 - 5869
[10] Photocatalysis for water decomposition by RuO2-dispersed ZnGa2O4 with d10 configuration
Ikarashi, K
Sato, J
Kobayashi, H
Saito, N
Nishiyama, H
Inoue, Y
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (35) : 9048 - 9053

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