Nucleation-growth processes of scale crystallization under electrochemical reaction investigated by in situ microscopy

被引:15
作者
Devos, O [1 ]
Gabrielli, C [1 ]
Tribollet, B [1 ]
机构
[1] Univ Paris 06, CNRS, UPR15, F-75252 Paris 05, France
关键词
D O I
10.1149/1.1396696
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Crystallization processes were investigated by in situ microscopic observation through a transparent electrode. In calcareous scale deposition, the technique led the nucleation-growth process of each crystalline form to be studied vs. time. During the first moments of growth, where overlapping did not occur, the number of particles and the area of each individual crystal increased linearly with time (t) in the present experimental conditions. Consequently, the total covered surface was proportional to t(2) showing a progressive nucleation. (C) 2001 The Electrochemical Society.
引用
收藏
页码:C73 / C76
页数:4
相关论文
共 11 条
[1]   Investigation of electrochemical calcareous scaling - Nuclei counting and morphology [J].
Beaunier, L ;
Gabrielli, C ;
Poindessous, G ;
Maurin, G ;
Rosset, R .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 501 (1-2) :41-53
[2]   In situ investigation of crystallization processes by coupling of electrochemical and optical measurements -: Application to CaCO3 deposit [J].
Cachet, H ;
Devos, O ;
Folcher, G ;
Gabrielli, C ;
Perrot, H ;
Tribollet, B .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (04) :C23-C25
[3]  
CACHET H, 2000, P 7 INT S EL METH CO
[4]   MASS-TRANSFER TO AN IMPINGING JET ELECTRODE [J].
CHIN, DT ;
TSANG, CH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (09) :1461-1470
[5]   A cell to study in situ electrocrystallization of calcium carbonate [J].
Euvrard, M ;
Filiatre, C ;
Crausaz, E .
JOURNAL OF CRYSTAL GROWTH, 2000, 216 (1-4) :466-474
[6]   Nucleation and growth of calcium carbonate by an electrochemical scaling process [J].
Gabrielli, C ;
Maurin, G ;
Poindessous, G ;
Rosset, R .
JOURNAL OF CRYSTAL GROWTH, 1999, 200 (1-2) :236-250
[7]  
Gabrielli C, 1996, J APPL ELECTROCHEM, V26, P1125
[8]   Quartz crystal microbalance investigation of electrochemical calcium carbonate scaling [J].
Gabrielli, C ;
Keddam, M ;
Khalil, A ;
Maurin, G ;
Perrot, H ;
Rosset, R ;
Zidoune, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (07) :2386-2396
[9]  
Ledion J., 1985, TSM LEAU, P323
[10]  
LIN W, 1990, TSM EAU DEC, P613