8-PropargylaminoBODIPY: unprecedented blue-emitting pyrromethene dye. Synthesis, photophysics and laser properties

被引:119
作者
Azael Gomez-Duran, C. F. [2 ]
Garcia-Moreno, Inmaculada [1 ]
Costela, Angel [1 ]
Martin, Virginia [1 ]
Sastre, Roberto [4 ]
Banuelos, Jorge [3 ]
Lopez Arbeloa, Fernando [3 ]
Lopez Arbeloa, Inigo [3 ]
Pena-Cabrera, Eduardo [2 ]
机构
[1] CSIC, Inst Quim Fis Rocasolano, Madrid 28006, Spain
[2] Univ Guanajuato, Dept Quim, Guanjuato, Gto, Mexico
[3] Univ Basque Country, Dept Quim Fis, EHU, E-48080 Bilbao, Spain
[4] CSIC, Inst Ciencia & Tecnol Polimeros, E-28006 Madrid, Spain
关键词
BODIPY DYES; BORONDIPYRROMETHENE; CHEMISTRY;
D O I
10.1039/c0cc00397b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly emitting 8-propargylaminoBODIPY (8-PAB) 2 was prepared in 94% yield. Unlike any other BODIPY structure hitherto described in the literature, 2 displays efficient emission in the blue region of the visible spectrum with a fluorescence quantum yield up to 0.94 and high laser efficiency (35%) at 483 nm.
引用
收藏
页码:5103 / 5105
页数:3
相关论文
共 21 条
[1]   Photophysical Study of Blue, Green, and Orange-Red Light-Emitting Carbazoles [J].
Adhikari, Ravi M. ;
Neckers, Douglas C. ;
Shah, Bipin K. .
JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (09) :3341-3349
[2]   Structural, photophysical and lasing properties of pyrromethene dyes [J].
Arbeloa, FL ;
Bañuelos, J ;
Martínez, V ;
Arbeloa, T ;
Arbeloa, IP .
INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 2005, 24 (02) :339-374
[3]   The Smallest and One of the Brightest. Efficient Preparation and Optical Description of the Parent Borondipyrromethene System [J].
Arroyo, Ismael J. ;
Hu, Rongrong ;
Merino, Gabriel ;
Tang, Ben Zhong ;
Pena-Cabrera, Eduardo .
JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (15) :5719-5722
[4]   Lighting the way ahead with boron dipyrromethene (Bodipy) dyes [J].
Benniston, Andrew C. ;
Copley, Graeme .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (21) :4124-4131
[5]  
Brackmann U., 2000, Laser dyes
[6]  
Costela A., 2001, HDB ADV ELECT PHOTON, V7, P161
[7]   Synthesis of 8-heteroatom-substituted 4,4-difluoro-4-bora-3a, 4a-diaza-s-indacene dyes (BODIPY) [J].
Goud, Thirumani Venkateshwar ;
Tutar, Ahmet ;
Biellmann, Jean-Francois .
TETRAHEDRON, 2006, 62 (21) :5084-5091
[8]  
HAMACHI I, 2009, Patent No. 20090233373
[9]  
Haugland R.P., 2005, HDB GUIDE FLUORESCEN, V10th
[10]   BODIPY dyes and their derivatives: Syntheses and spectroscopic properties [J].
Loudet, Aurore ;
Burgess, Kevin .
CHEMICAL REVIEWS, 2007, 107 (11) :4891-4932