Oxidation of alpha,beta-enones and alkenes with oxone and sodium halides: A convenient laboratory preparation of chlorine and bromine

被引：122

作者：

Dieter, RK

Nice, LE

Velu, SE

机构：

[1] Hunter Laboratory, Department of Chemistry, Clemson University, Clemson

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 14期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(96)00295-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mixtures of oxone and sodium chloride or sodium bromide afford solutions of chlorine or bromine, respectively. These solutions effectively add chlorine and bromine to alpha,beta-enones and alkenes. The method affords improved yields of 3-alkyl-2-halo-2-cycloalkenones which are sometimes difficult to prepare. Copyright (C) 1996 Elsevier Science Ltd

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页码：2377 / 2380

页数：4

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