Synthesis, characterization and crystal structure of [Pt(Me)(dppe){η1-CH(PPh3)(COOEt)}]BF4.: An example of overcrowded molecule and correlated properties

被引：8

作者：

Benetollo, F

Bertani, R

Ganis, P ^{[1
]}

Pandolfo, L

Zanotto, L

机构：

[1] Univ Padua, Dipartimento Sci Fis, I-35131 Padua, Italy

[2] Univ Padua, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy

[3] CNR, ICTIMA, I-35100 Padua, Italy

[4] Univ Basilicata, Dipartimento Chim, I-85100 Potenza, Italy

[5] CNR, CSTCMET, I-35131 Padua, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 629卷 / 1-2期

关键词：

crystal structures; platinum; metal complexes; phosphorus ylides;

D O I：

10.1016/S0022-328X(01)00864-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Pt(Me)(dppe){eta (1)-CH(PPh3)(COOEt)}]BF4 has been synthesized and characterized spectroscopically and structurally. It crystallizes in the space group P2(1)/n, with lattice constants a = 14.525(3) Angstrom, b = 14.931(3) Angstrom, c = 21.921(4) Angstrom, beta = 103.47(3)degrees. The X-ray analysis revealed a particularly overcrowded molecular structure containing high stereochemical constraints. The structural features account for specific chemical and physical properties of this compound, thus representing an interesting example of applied crystallography. (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：201 / 207

页数：7

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