Structures in dissociative electron attachment cross-sections in thymine, uracil and halouracils

被引:58
作者
Abouaf, R [1 ]
Dunet, H [1 ]
机构
[1] Univ Paris 11, Collis Atom & Mol Lab, UMR 8625, F-91405 Orsay, France
关键词
D O I
10.1140/epjd/e2005-00239-9
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The low energy parts (0-3 eV) of the dissociative electron attachment (DEA) cross-sections in uracil, thymine, and the halouracils 5-BrU, 5-ClU, 6-ClU, 5-FU, have been revisited with an improved energy resolution, focussing onto the puzzling structures observed on most cross-sections of the various anions fragments versus electron energy. The elastic electron scattering cross-sections near zero energy have also been recorded. In most cases they present a few features (cusps) related to the low energy peaks found in DEA cross-sections. Substantial differences are found in the detailed spectra of the fragments produced in 5-ClU and 6-ClU. Several interpretations already proposed to explain the previous observations, in terms of different thresholds and/or contributions of vibrational Feshbach resonances, and their limits, are discussed in the light of our new results. We expect that our more detailed results will stimulate theoretical work for a better understanding of the features observed.
引用
收藏
页码:405 / 410
页数:6
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