First syntheses of fused pyrroloporphyrins

被引：74

作者：

Jaquinod, L ^{[1
]}

Gros, C ^{[1
]}

Olmstead, MM ^{[1
]}

Antolovich, M ^{[1
]}

Smith, KM ^{[1
]}

机构：

[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 12期

关键词：

D O I：

10.1039/cc9960001475

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(2-Nitro-5,10,15,20-tetraphenylporphyrinato)nickel(II) reacts with alpha-isocyanoacetic esters in the presence of DBU to give the first beta-fused pyrroloporphyrins, the pyrrole ring in the fused system being shown to undergo typical pyrrole-type chemistry; the corresponding zinc(II) complex affords a novel cyclopropanochlorin (characterized by X-ray crystallography), when treated with an alpha-isocyanoacetic ester.

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页码：1475 / 1476

页数：2

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