Thermal behaviour of urea-formaldehyde resins during curing

被引:115
作者
Siimer, K [1 ]
Kaljuvee, T [1 ]
Christjanson, P [1 ]
机构
[1] Tallinn Univ Technol, EE-19086 Tallinn, Estonia
关键词
curing; polycondensation; storage; TG-DTA technique; urea-formaldehyde resins;
D O I
10.1023/A:1024590019244
中图分类号
O414.1 [热力学];
学科分类号
摘要
Urea-formaldehyde (UF) resins are the most widely used polycondensation resins today in manufacturing particleboards. The performance of UF resins in their processing is greatly influenced by curing characteristics. The cure process has been monitored by TG-DTA technique on a Setaram labsys(TM) instrument in dynamic heating conditions at different heating rates. Commercial UF resins from different suppliers used in Estonian particleboard factories were selected for TG-DTA measurements. Experiments were carried out without and with catalysts. Ammonium chloride and ammonium sulphate were used. Curing characteristics were evaluated both for fresh and aged resins.
引用
收藏
页码:607 / 617
页数:11
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