Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes

被引：77

作者：

Kaspi, Ariela W. ^{[1
]}

Yahav-Levi, Anette ^{[1
]}

Goldberg, Israel ^{[1
]}

Vigalok, Arkadi ^{[1
]}

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 01期

关键词：

D O I：

10.1021/ic701722f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium(II) aryliodo complexes bearing chelating diphosphine ligands react with XeF2, giving iodoarene and rare palladium(II) difluoro complexes. The reaction is general with regard to the aryl group, with even C6F5-I undergoing facile reductive elimination from a Pd center.

引用

页码：5 / 7

页数：3

共 26 条

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