Synthesis and characterization of novel polyvalent organoiodine compounds

被引：28

作者：

Meprathu, BV

Protasiewicz, JD ^{[1
]}

机构：

[1] Case Western Reserve Univ, Dept Chem, Cleveland, OH 44106 USA

[2] Case Western Reserve Univ, Ctr Canc, Cleveland, OH 44106 USA

来源：

ARKIVOC | 2003年

关键词：

polyvalent organoiodine compounds; PhINTs; PhIO; secondary bonding;

D O I：

10.3998/ark.5550190.0004.610

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis and characterization of soluble analogues of iodosylbenzene PhIO and (tosyliminoiodo) benzene PhINTs are reported. The syntheses of 4-trifluoromethyl-2-(tertbutylsulfonyl) iodosylbenzene (3) and 4-trifluoromethyl- 2-(tert-butylsulfonyl)( tosylimino) iodobenzene ( 4) increase the repertoire of available soluble organoiodine(III) based oxo- and nitrene precursors. We also report the synthesis of a new organoiodine( V) compound, 4-trifluoromethyl- 2-( tert-butylsulfonyl) iodylbenzene.

引用

收藏

页码：83 / 90

页数：8

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