Highly active, reusable and moisture insensitive catalyst obtained from basic Ga-Mg-hydrotalcite anionic clay for Friedel-Crafts type benzylation and acylation reactions

Liquid phase benzylation (by benzyl chloride) and acylation (by benzoyl chloride) of benzene and toluene over a Ga-Mg hydrotalcite (which is a basic anionic clay) with or without HCl gas pretreatment and also over the hydrotalcite used earlier in the toluene benzylation (at 110 degreesC) have been investigated. The fresh, used and HCl-gas-pretreated hydrotalcite catalysts were characterized for their surface area, basicity, crystalline structure and phases and also for their surface composition. The fresh hydrotalcite showed no catalytic activity for both the benzylation and benzoylation reactions for a long period. However, after a long induction period (2.7 h), the catalyst showed a very high activity in the toluene benzylation (at 110 degreesC). Whereas, the catalyst after its use in the toluene benzylation or after its HCl gas pretreatment showed very high activity for both the reactions with a much shorter induction period. The hydrotalcite-derived catalyst consists essentially highly dispersed gallium and magnesium chlorides on MgO. The presence of moisture in the reaction mixture has beneficial effects on the acylation reactions over the used catalyst.