Metallocryptands: Host complexes for probing closed-shell metal-metal interactions

被引：30

作者：

Catalano, VJ ^{[1
]}

Bennett, BL ^{[1
]}

Malwitz, MA ^{[1
]}

Yson, RL ^{[1
]}

Kar, HM ^{[1
]}

Muratidis, S ^{[1
]}

Horner, SJ ^{[1
]}

机构：

[1] Univ Nevada, Dept Chem, Reno, NV 89557 USA

来源：

COMMENTS ON INORGANIC CHEMISTRY | 2003年 / 24卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

metallocryptands; metal-metal interactions; encapsulation; cage; liminescence;

D O I：

10.1080/02603590390237236

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metallocryptands are inorganic host complexes that contain a central metal ion, around which are arranged three multi-denate ligands capped by a trigonally coordinated d(10) transition metal (Pt(0), Pd(0), and Au(1)). These very large cage complexes are capable of incarcerating a variety of metals, metal ions and anions including alkali metal ions, Hg-2(2+) , Hg-0 , Tl+ , Pb2+ and with modification the halides. Many of the metal-metal interactions within these complexes are shorter than the sum of the respective covalent radii often resulting in complexes that are highly luminescent.

引用

页码：39 / 68

页数：30

共 36 条

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