Solvothermal synthesis of K2V3O8 nanorods

被引:15
作者
Xu, HY [1 ]
He, WL [1 ]
Wang, H [1 ]
Yan, H [1 ]
机构
[1] Beijing Univ Technol, Dept Mat Sci & Engn, Key Lab Adv Funct Mat China Educ Minist, Beijing 100022, Peoples R China
关键词
growth from solutions; nanomaterials; vanadates; magnetic materials;
D O I
10.1016/j.jcrysgro.2003.08.051
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A solvothermal route has been developed to synthesize K2V3O8 nanorods via the reduction of V2O5 using ethanol as the reducing agent as well as the solvent at 200degreesC. X-ray diffraction and selected area electron diffraction analysis revealed that the as-synthesized products are of tetragonal structure K2V3O8. Transmission electron spectroscopy image showed that the obtained K2V3O8 comprises rod-like nanocrystallites. The formation mechanism of K2V3O8 was studied. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:447 / 450
页数:4
相关论文
共 15 条
[1]   Magnetic structures and reorientation transitions in noncentrosymmetric uniaxial antiferromagnets -: art. no. 214410 [J].
Bogdanov, AN ;
Rössler, UK ;
Wolf, M ;
Müller, KH .
PHYSICAL REVIEW B, 2002, 66 (21) :1-16
[2]   Local symmetry breaking in K2V3O8 as studied by infrared spectroscopy -: art. no. 054101 [J].
Choi, J ;
Zhu, ZT ;
Musfeldt, JL ;
Ragghianti, G ;
Mandrus, D ;
Sales, BC ;
Thompson, JR .
PHYSICAL REVIEW B, 2002, 65 (05) :1-6
[3]   CRYSTAL-STRUCTURE OF K2V3O8 OR K2(VO)[V2O7] [J].
GALY, J ;
CARPY, A .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (JUN15) :1794-1795
[4]   A NEW ACCESS TO ALKALI VANADATES(IV,V) CRYSTAL-STRUCTURE OF RB2V3O8 [J].
HAEIERDANZ, ML ;
MULLER, U .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 613 (07) :63-66
[5]   MAGNETIC-PROPERTIES OF FRESNOITE-TYPE VANADIUM-OXIDES - A(2)V(3)O(8) (A=K, RB, NH4) [J].
LIU, G ;
GREEDAN, JE .
JOURNAL OF SOLID STATE CHEMISTRY, 1995, 114 (02) :499-505
[6]   Weak ferromagnetism and field-induced spin reorientation in K2V3O8 [J].
Lumsden, MD ;
Sales, BC ;
Mandrus, D ;
Nagler, SE ;
Thompson, JR .
PHYSICAL REVIEW LETTERS, 2001, 86 (01) :159-162
[7]   FRESNOITE - UNUSAL TITANIUM COORDINATION [J].
MOORE, PB ;
LOUISNATHAN, J .
SCIENCE, 1967, 156 (3780) :1361-+
[8]  
RANGE KJ, 1988, Z NATURFORSCH B, V43, P309
[9]   Magnetic field enhancement of heat transport in the 2D Heisenberg antiferromagnet K2V3O8 -: art. no. 095901 [J].
Sales, BC ;
Lumsden, MD ;
Nagler, SE ;
Mandrus, D ;
Jin, R .
PHYSICAL REVIEW LETTERS, 2002, 88 (09) :4
[10]   CRYSTAL-GROWTH, STRUCTURE, ELECTRON-PARAMAGNETIC RESONANCE AND MAGNETIC-PROPERTIES OF (NH4)2V3O8 [J].
THEOBALD, FR ;
THEOBALD, JG ;
VEDRINE, JC ;
CLAD, R ;
RENARD, J .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1984, 45 (06) :581-587