Incorporating BODIPY Fluorophores into Tetrakis(arylethynyl)benzenes

被引：25

作者：

Chase, Daniel T.

Young, Brian S.

Haley, Michael M. ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 10期

基金：

美国国家科学基金会;

关键词：

STRUCTURE-PROPERTY RELATIONSHIPS; EFFICIENT ENERGY-TRANSFER; FLUORESCENT-PROBE; DYES; TETRAKIS(PHENYLETHYNYL)BENZENES; CHEMISTRY; DESIGN; ION; CHROMOPHORE; RADIOLYSIS;

D O I：

10.1021/jo200491m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Six structural isomers of a tetrakis(arylethynyl)benzene (TAEB) chromophore functionalized with dibutylamine and BODIPY moieties as the corresponding donor and acceptor units were prepared. To evaluate the effectiveness of the donor group, two TAEB molecules and three structurally related bis(arylethynyl)benzene (BAEB) isomers containing only acceptors were also synthesized. The electronic absorption and emission spectra of each series were examined. Additionally, computational studies were employed to corroborate the relative energy levels and gaps present in each series.

引用

页码：4043 / 4051

页数：9

共 59 条

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[2]

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