Crystal growth of perylene microcrystals in the reprecipitation method

被引：99

作者：

Kasai, H ^{[1
]}

Oikawa, H ^{[1
]}

Okada, S ^{[1
]}

Nakanishi, H ^{[1
]}

机构：

[1] Tohoku Univ, Inst Chem React Sci, Aoba Ku, Sendai, Miyagi 9808577, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1998年 / 71卷 / 11期

关键词：

D O I：

10.1246/bcsj.71.2597

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal growth of alpha-perylene microcrystals in the reprecipitation method was studied using of light-scattering technique and absorption spectroscopy. A certain model for microcrystallization has been established. The relationship between the reprecipitation conditions and the crystal size was clarified on the basis of this model. Especially, the water temperature was confirmed to be one of the most important parameters used to control the size of the microcrystals in the reprecipitation method. The apparent activation energy for the microcrystallization of perylene was estimated to be 68 kJ mol(-1).

引用

页码：2597 / 2601

页数：5

共 24 条

[1] ELECTRON ELECTRON AND ELECTRON-HOLE INTERACTIONS IN SMALL SEMICONDUCTOR CRYSTALLITES - THE SIZE DEPENDENCE OF THE LOWEST EXCITED ELECTRONIC STATE [J].

BRUS, LE .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (09) :4403-4409

[2] STABILITY OF AMORPHOUS COLLOIDAL SILICA [J].

DEPASSE, J ;

WATILLON, A .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1970, 33 (03) :430-&

[3] QUANTUM SIZE EFFECT IN SEMICONDUCTOR MICROCRYSTALS [J].

EKIMOV, AI ;

EFROS, AL ;

ONUSHCHENKO, AA .

SOLID STATE COMMUNICATIONS, 1985, 56 (11) :921-924

[4] OPTICAL-PROPERTIES OF CONJUGATED POLYMER SUPERLATTICES PREPARED BY POTENTIAL-PROGRAMMED ELECTROPOLYMERIZATION [J].

FUJITSUKA, M ;

NAKAHARA, R ;

IYODA, T ;

SHIMIDZU, T ;

TSUCHIYA, H .

JOURNAL OF APPLIED PHYSICS, 1993, 74 (02) :1283-1286

[5] VERY LARGE OPTICAL NONLINEARITY OF SEMICONDUCTOR MICROCRYSTALLITES [J].

HANAMURA, E .

PHYSICAL REVIEW B, 1988, 37 (03) :1273-1279

[6] Solid-state polymerization of diacetylene microcrystals [J].

Iida, R ;

Kamatani, H ;

Kasai, H ;

Okada, S ;

Oikawa, H ;

Matsuda, H ;

Kakuta, A ;

Nakanishi, H .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1995, 267 :95-100

[7] Size-dependent colors and luminescences of organic microcrystals [J].

Kasai, H ;

Kamatani, H ;

Okada, S ;

Oikawa, H ;

Matsuda, H ;

Nakanishi, H .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1996, 35 (2B) :L221-L223

[8] Optical properties of perylene microcrystals [J].

Kasai, H ;

Yoshikawa, Y ;

Seko, T ;

Okada, S ;

Oikawa, H ;

Mastuda, H ;

Watanabe, A ;

Ito, O ;

Toyotama, H ;

Nakanishi, H .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1997, 294 :173-176

[9] A NOVEL PREPARATION METHOD OF ORGANIC MICROCRYSTALS [J].

KASAI, H ;

NALWA, HS ;

OIKAWA, H ;

OKADA, S ;

MATSUDA, H ;

MINAMI, N ;

KAKUTA, A ;

ONO, K ;

MUKOH, A ;

NAKANISHI, H .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1992, 31 (8A) :L1132-L1134

[10]

Kasai H., 1996, Nonlinear Optics, Principles, Materials, Phenomena, and Devices, V15, P263

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