Catalytic hydrodechlorination of chlorobenzene in liquid phase

被引：19

作者：

Benítez, JL

Del Angel, G

机构：

[1] Inst Mexicano Petr, Dept Desarrollo Prod Quim, Mexico City 07730, DF, Mexico

[2] Univ Autonoma Metropolitana Iztapalapa, Dept Quim, Mexico City 09340, DF, Mexico

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1999年 / 66卷 / 01期

关键词：

hydrodechlorination; chlorobenzene; Pd/C; solvent effect;

D O I：

10.1007/BF02475735

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic hydrodechlorination of chlorobenzene (CB) was carried out in the liquid phase in a mixture of methanol/water (MeOH/H2O) at 30 degrees C and 2 kg/cm(2) pressure. The reaction orders with respect to CB and H-2 pressure were one and zero, respectively. Addition of NH4OH in the reaction produces a decrease in the activity (TOF). Solvent effect shows the following order of activity: H2O > MeOH/H2O > EtOH/H2O > MeOH.

引用

页码：13 / 18

页数：6

共 13 条

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ARMOR JN, 1995, APPL CATAL B, V5

[2] EXHAUSTIVE LIQUID-PHASE CATALYTIC HYDRODEHALOGENATION OF CHLOROBENZENES [J].