Low temperature μc-Si film growth using a CaF2 seed layer

被引:7
作者
Kim, DY [1 ]
Ahn, BJ [1 ]
Moon, SI [1 ]
Won, CY [1 ]
Yi, J [1 ]
机构
[1] Sungkyunkwan Univ, Sch Elect & Comp Engn, Jangan Gu, Suwon 440746, Kyunggi Do, South Korea
关键词
mu c-Si; RPCVD; CaF2; seed layer; low temperature growth;
D O I
10.1016/S0927-0248(01)00032-0
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
This paper describes low temperature thin film Si growth by remote plasma chemical vapor deposition system for photovoltaic device applications. Using CaF2/glass substrate. we were able to achieve an improved pc-Si film at a low process temperature of 300 degreesC. The muc-Si film on CaF2/glass substrate shows that a crystalline volume fraction of 65% and dark conductivity of 1.65 x 10(-8) S/cm with the growth conditions of 50 W, 300 degreesC, 88 mTorr, and SiH4/H-2 = 1.2%. XRD analysis on muc-Si/CaF2 /glass showed crystalline film growth in (111) and (220) planes. Grain size was enlarged as large as 700 Angstrom for a muc-Si/CaF2/glass structure. Activation energy of muc-Si film was given as 0.49 eV. The muc-Si films exhibited dark-and photo-conductivity ratio of 124. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:415 / 423
页数:9
相关论文
共 10 条
[1]   Deposition of microcrystalline silicon in an integrated distributed electron cyclotron resonance PECVD reactor [J].
Bulkin, P ;
Hofrichter, A ;
Brenot, R ;
Drévillon, B .
THIN SOLID FILMS, 1999, 337 (1-2) :37-40
[2]  
CULLITY BD, 1978, ELEMENTS XRAY DIFFRA, P365
[3]   THE STRUCTURE AND PROPERTIES OF NANOSIZE CRYSTALLINE SILICON FILMS [J].
HE, YL ;
YIN, CZ ;
CHENG, GX ;
WANG, LC ;
LIU, XN ;
HU, GY .
JOURNAL OF APPLIED PHYSICS, 1994, 75 (02) :797-803
[4]   Amorphous and microcrystalline silicon by hot wire chemical vapor deposition [J].
Heintze, M ;
Zedlitz, R ;
Wanka, HN ;
Schubert, MB .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (05) :2699-2706
[5]  
JANG J, 1999, SID, V30, P728
[6]   Preparation of high-quality undoped microcrystalline silicon with high deposition rate using mercury-sensitized photochemical vapor deposition method [J].
Jang, JH ;
Lim, KS .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1996, 35 (11) :5625-5630
[7]  
Lindmayer J., 1980, Fourteenth IEEE Photovoltaic Specialists Conference 1980, P208
[8]   Control of orientation for polycrystalline silicon thin films fabricated from fluorinated source gas by microwave plasma enhanced chemical vapor deposition [J].
Nakahata, K ;
Miida, A ;
Kamiya, T ;
Maeda, Y ;
Fortmann, CM ;
Shimizu, I .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1998, 37 (9AB) :L1026-L1029
[9]  
WAKAGI M, 1993, MAT RES S C, V283, P555
[10]  
YANG LY, 1993, MAT RES S C, V283, P463