Bismuth compounds in organic synthesis. Deprotection of ketoximes using bismuth bromide-bismuth triflate

被引：26

作者：

Arnold, JN ^{[1
]}

Hayes, PD ^{[1
]}

Kohaus, RL ^{[1
]}

Mohan, RS ^{[1
]}

机构：

[1] Illinois Wesleyan Univ, Dept Chem, Lab Environm Friendly Organ Synth, Bloomington, IL 61701 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 51期

关键词：

bismuth and compounds; oximes; deprotection; environment-friendly chemistry;

D O I：

10.1016/j.tetlet.2003.10.031

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ketoximes undergo deprotection in CH3CN/acetone/H2O (3:6:1) in the presence of 20-40 mol% BiBr3/5 mol% Bi(OTf)(3). Bismuth(III) salts are relatively non-toxic, insensitive to air and inexpensive. These features coupled with the use of a relatively non-toxic solvent system make this method an attractive alternative to existing routes for deprotection of ketoximes. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：9173 / 9175

页数：3

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