Novel organic ionic liquids (OILs) incorporating cations derived from the antifungal drug miconazole.

被引：110

作者：

Davis, JH ^{[1
]}

Forrester, KJ ^{[1
]}

Merrigan, T ^{[1
]}

机构：

[1] Univ S Alabama, Dept Chem, Mobile, AL 36608 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 49期

关键词：

ionic liquids; liquid crystals; antifungals; imidazoles;

D O I：

10.1016/S0040-4039(98)02070-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The imidazole-ring containing antifungal drug miconazole reacts with a variety of alkyl iodides to form imidazolium cations. After anion metathesis with NaPF6, organic ionic liquids (OILs) are obtained. These new ionic liquids are believed to be the first to be derived from a bioactive molecule, One of the new OILs also exhibits lyotropic liquid crystalline behavior while inducing the gelation of benzene. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：8955 / 8958

页数：4

共 6 条

[1] [Anonymous], J CHEM SOC CHEM COMM
[2] Hydrophobic, highly conductive ambient-temperature molten salts
Bonhote, P
Dias, AP
Papageorgiou, N
Kalyanasundaram, K
Gratzel, M
[J]. INORGANIC CHEMISTRY, 1996, 35 (05) : 1168 - 1178
[3] DAVIS JH, 1998, IN PRESS INORG CHEM, V37
[4] HYDROGEN-BONDING IN IMIDAZOLIUM SALTS AND ITS IMPLICATIONS FOR AMBIENT-TEMPERATURE HALOGENOALUMINATE(III) IONIC LIQUIDS
ELAIWI, A
HITCHCOCK, PB
SEDDON, KR
SRINIVASAN, N
TAN, YM
WELTON, T
ZORA, JA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (21): : 3467 - 3472
[5] ROOM-TEMPERATURE HALOALUMINATE IONIC LIQUIDS - NOVEL SOLVENTS FOR TRANSITION-METAL SOLUTION CHEMISTRY
HUSSEY, CL
[J]. PURE AND APPLIED CHEMISTRY, 1988, 60 (12) : 1763 - 1772
[6] LU L, 1996, J CHEM SOC CHEM COMM, P2029

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