Novel organic ionic liquids (OILs) incorporating cations derived from the antifungal drug miconazole.

被引:110
作者
Davis, JH [1 ]
Forrester, KJ [1 ]
Merrigan, T [1 ]
机构
[1] Univ S Alabama, Dept Chem, Mobile, AL 36608 USA
关键词
ionic liquids; liquid crystals; antifungals; imidazoles;
D O I
10.1016/S0040-4039(98)02070-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The imidazole-ring containing antifungal drug miconazole reacts with a variety of alkyl iodides to form imidazolium cations. After anion metathesis with NaPF6, organic ionic liquids (OILs) are obtained. These new ionic liquids are believed to be the first to be derived from a bioactive molecule, One of the new OILs also exhibits lyotropic liquid crystalline behavior while inducing the gelation of benzene. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:8955 / 8958
页数:4
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