A cobalt-free oxygen-permeable membrane based on the perovskite-type oxide Ba0.5Sr0.5Zn0.2Fe0.8O3-δ

被引:237
作者
Wang, HH [1 ]
Tablet, C [1 ]
Feldhoff, A [1 ]
Caro, J [1 ]
机构
[1] Leibniz Univ Hannover, Inst Phys Chem & Electrochem, D-30167 Hannover, Germany
关键词
D O I
10.1002/adma.200401608
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Zn-containing perovskite structure of composition Ba0.5Sr0.5Zn0.2Fe0.8O3-delta, is proposed as an oxygen-transport material with good phase stability at low oxygen partial pressures at temperatures up to 950 degrees C. The material has been successfully tested in a membrane reactor in the partial oxidation of methane to synthesis gas (see Figure).
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页码:1785 / +
页数:5
相关论文
共 21 条
[1]   Controlled oxidative coupling of methane by ionic conducting ceramic membrane [J].
Akin, FT ;
Lin, YS .
CATALYSIS LETTERS, 2002, 78 (1-4) :239-242
[2]   Structural, electrical and electrochemical properties of co-precipitated SrFeO3-δ [J].
Augustin, CO ;
Berchmans, LJ ;
Selvan, RK .
MATERIALS LETTERS, 2004, 58 (7-8) :1260-1266
[3]   Ceramic membrane reactor for converting methane to syngas [J].
Balachandran, U ;
Dusek, JT ;
Maiya, PS ;
Ma, B ;
Mieville, RL ;
Kleefisch, MS ;
Udovich, CA .
CATALYSIS TODAY, 1997, 36 (03) :265-272
[4]   Dense ceramic membranes for methane conversion [J].
Bouwmeester, HJM .
CATALYSIS TODAY, 2003, 82 (1-4) :141-150
[5]  
Chen CS, 2001, ANGEW CHEM INT EDIT, V40, P784, DOI 10.1002/1521-3773(20010216)40:4<784::AID-ANIE7840>3.0.CO
[6]  
2-H
[7]  
CHEN S, 2003, ANGEW CHEM INT EDIT, V115, P5354
[8]   Ion transport membrane technology for oxygen separation and syngas production [J].
Dyer, PN ;
Richards, RE ;
Russek, SL ;
Taylor, DM .
SOLID STATE IONICS, 2000, 134 (1-2) :21-33
[9]   Surface enhanced oxygen permeation in CaTi1-xFexO3-δ ceramic membranes [J].
Figueiredo, FM ;
Kharton, VV ;
Viskup, AP ;
Frade, JR .
JOURNAL OF MEMBRANE SCIENCE, 2004, 236 (01) :73-80
[10]   Methane oxidation on the surface of mixed-conducting La0.3Sr0.7Co0.8Ga0.2O3-δ [J].
Kharton, VV ;
Sobyanin, VA ;
Belyaev, VD ;
Semin, GL ;
Veniaminov, SA ;
Tsipis, EV ;
Yaremchenko, AA ;
Valente, AA ;
Marozau, IP ;
Frade, JR ;
Rocha, J .
CATALYSIS COMMUNICATIONS, 2004, 5 (06) :311-316