A phenoxyl radical complex of copper(II)

被引:106
作者
Benisvy, L
Blake, AJ
Collison, D
Davies, ES
Garner, CD
McInnes, EJL
McMaster, J
Whittaker, G
Wilson, C
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[3] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
D O I
10.1039/b105186p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new NO-bidentate pro-ligand (HL), [ML2] (M = Cu, Zn) and [CuL2][BF4] have been synthesised; [CuL2]. 4DMF and [CuL2][BF4]. 2CH(2)Cl(2) have been crystallographically and spectroscopically characterised; these data indicate that [CuL2](+) cations are constituted as [Cu2+(L-.)(L-)](+) and involve the phenoxyl radical L-..
引用
收藏
页码:1824 / 1825
页数:2
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