Pronounced supramolecular order in discotic donor-acceptor mixtures

被引：134

作者：

Pisula, W ^{[1
]}

Kastler, M ^{[1
]}

Wasserfallen, D ^{[1
]}

Robertson, JWF ^{[1
]}

Nolde, F ^{[1
]}

Kohl, C ^{[1
]}

Müllen, K ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 05期

关键词：

dyes/pigments; helical structures; homeotropic phases; supramolecular chemistry;

D O I：

10.1002/anie.200500669

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mixing a hexa-peri-hexabenzocoronene (HBC) derivative and a perylene- or terrylenediimide results in the formation of complex helical arrangements in the columnar superstructures. Weak donor-acceptor interactions between the electron-rich HBC and the electron-poor rylene dye lead to strictly alternating and long-range-ordered stacks. The mixtures display homeotropic orientation on surfaces (picture shows an image from an optical microscope). (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：819 / 823

页数：5

共 19 条

[1]

[Anonymous], 2000, ANGEW CHEM, DOI DOI 10.1002/1521-3757(20000703)112:13<2423::AID

[2]

Arikainen EO, 2000, ANGEW CHEM INT EDIT, V39, P2333, DOI 10.1002/1521-3773(20000703)39:13<2333::AID-ANIE2333>3.0.CO

[3]

2-V

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