Phencyclone Diels-Alder adducts as a new crystalline host.: Role of C-H•••π and C-H•••O interactions

被引：21

作者：

Eto, M ^{[1
]}

Setoguchi, K ^{[1
]}

Harada, A ^{[1
]}

Sugiyama, E ^{[1
]}

Harano, K ^{[1
]}

机构：

[1] Kumamoto Univ, Fac Pharmaceut Sci, Kumamoto 8620973, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(98)02283-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of crystalline host compounds, which have a bicyclo[2.2.1]heptene-7-one system, has been synthesized and their inclusion behavior has been investigated. The cycloadduct of phencyclone and N-naphthylmaleimide forms a 1:1 crystalline inclusion complex with 2-butanone. The crystal structure indicates the presence of weak lattice forces supported by C-H ...pi and C-H ... O interactions. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：9751 / 9754

页数：4

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