Hexyl-substituted oligothiophenes with a central tetrafluorophenylene unit: crystal engineering of planar structures for p-type organic semiconductors

被引：56

作者：

Crouch, DJ

Skabara, PJ

Heeney, M

McCulloch, I

Coles, SJ

Hursthouse, MB

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[2] MERCK Chem, Southampton SO16 7QD, Hants, England

[3] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 11期

关键词：

D O I：

10.1039/b417642a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rigidification has been achieved in thiophene - tetrafluorophenylene architectures through strong S center dot center dot center dot F and H center dot center dot center dot F intramolecular interactions; the resulting materials are promising candidates for p-type organic field effect transistors.

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收藏

页码：1465 / 1467

页数：3

相关论文

共 15 条

[1] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[2]

Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO

[3]

2-A

[4] Enhanced mobility of poly(3-hexylthiophene) transistors by spin-coating from high-boiling-point solvents [J].

Chang, JF ;

Sun, BQ ;

Breiby, DW ;

Nielsen, MM ;

Sölling, TI ;

Giles, M ;

McCulloch, I ;

Sirringhaus, H .

CHEMISTRY OF MATERIALS, 2004, 16 (23) :4772-4776

[5]

Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO

[6]

2-9

[7] Building blocks for n-type organic electronics: Regiochemically modulated inversion of majority carrier sign in perfluoroarene-modified polythiophene semiconductors [J].

Facchetti, A ;

Yoon, MH ;

Stern, CL ;

Katz, HE ;

Marks, TJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (33) :3900-3903

[8] A combined substituent and supramolecular approach for improving the electron donor properties of 1,3-dithiole-2-thione derivatives [J].

Khan, T ;

McDouall, JJW ;

McInnes, EJL ;

Skabara, PJ ;

Frère, P ;

Coles, SJ ;

Hursthouse, MB .

JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (10) :2490-2498

[9]

Kraft A, 1998, ANGEW CHEM INT EDIT, V37, P402, DOI 10.1002/(SICI)1521-3773(19980302)37:4<402::AID-ANIE402>3.0.CO

[10]

2-9