Characterization of ceramic-metal composite hydrogen separation membranes consisting of barium oxide, cerium oxide, yttrium oxide and palladium

被引：10

作者：

Siriwardane, RV

Poston, JA

Fisher, EP

Lee, TH

Dorris, SE

Balachandran, U

机构：

[1] US DOE, Natl Energy Technol Lab, Morgantown, WV 26507 USA

[2] Argonne Natl Lab, Div Energy Technol, Argonne, IL 60439 USA

来源：

APPLIED SURFACE SCIENCE | 2003年 / 217卷 / 1-4期

关键词：

high temperature membranes; hydrogen separation membranes; ceramic membranes; surface characterization of membranes;

D O I：

10.1016/S0169-4332(03)00562-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Cermet (ceramic-metal composite) hydrogen separation membranes consisting of barium oxide, cerium oxide, yttrium oxide and palladium were characterized by utilizing X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy/ energy dispersive spectroscopy (SEM/EDS). Characterization was performed at room temperature and 650 degreesC, and after exposure to hydrogen. Changes in both elemental composition and oxidation states were observed at elevated temperatures and as a function of time. Permeation of hydrogen through the membranes also changed with time and temperature. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：43 / 49

页数：7

共 4 条

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