Two-dimensional diffraction from enantiopure and racemic monolayers of [Ru(bpy)3]2+ intercalated into synthetic fluorohectorite

被引：20

作者：

Breu, J ^{[1
]}

Stoll, A

Lange, KG

Probst, T

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

[2] Tech Univ Munich, Inst Radiochem, D-85747 Garching, Germany

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2001年 / 3卷 / 07期

关键词：

D O I：

10.1039/b009939m

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

While for intercalation compounds of natural smectites 2D long range order of the interlamellar space was never observed, in-plane order can be detected using a homogeneously charged synthetic fluorohectorite as host material. With these intercalates distinct 2D structures for enantiopure and racemic [Ru(bpy)(3)](2+)-interlayers, as previously predicted by atomistic simulations, can now be proven experimentally.

引用

页码：1232 / 1235

页数：4

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