Ruthenium initiated ring opening metathesis polymerisation of amino-acid and -ester functionalised norbornenes and a highly selective chain-end functionalisation reaction using molecular oxygen

被引：46

作者：

Biagini, SCG

Davies, RG

Gibson, VC

Giles, MR

Marshall, EL

North, M

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] Kings Coll London, Dept Chem, London WC2R 2LS, England

来源：

POLYMER | 2001年 / 42卷 / 15期

基金：

英国工程与自然科学研究理事会;

关键词：

ruthenium; polymerisation; metathesis;

D O I：

10.1016/S0032-3861(01)00146-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

[Ru(=CHPh)(PCy3)(2)Cl-2] is shown to initiate the living ring opening metathesis polymerisation of amino-acid and -ester functionalised norbornenes; treatment of the living polymers with molecular oxygen gives rise to a highly selective chain-end functionalisation reaction. (C) 2001 Elsevier 2001 Elsevier Science Ltd, Ail rights reserved.

引用

收藏

页码：6669 / 6671

页数：3

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