A high dynamic PEM fuel cell model with temperature effects

被引:123
作者
Shan, YY [1 ]
Choe, SY [1 ]
机构
[1] Auburn Univ, Dept Mech Engn, Auburn, AL 36830 USA
关键词
PEMFC; dynamic; temperature; water; efficiency; startup;
D O I
10.1016/j.jpowsour.2004.12.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Safe and reliable operation of a fuel cell requires proper management of the water and heat that are produced as by-products. Most of the current models for the cell used for an analysis of the fuel cell system are based on the empirical polarization curve and neglect the dynamic effects of water concentration, temperature and reactant distribution on the characteristics. The new model proposed in this paper is constructed upon the layers of a cell, taking into account the following factors: (1) dynamics in temperature gradient across the fuel cell; (2) dynamics in water concentration redistribution in the membrane; (3) dynamics in proton concentration in the cathode catalyst layer; (4) dynamics in reactant concentration redistribution in the cathode GDL. Simulations have been performed to analyze the effects of load currents on the behaviors of the fuel cell. In the future, the fuel cell model will be extended to a stack model and integrated with system models. All of the models will be implemented on a real time system that optimizes the computation time by a parallelization of solvers, which provides an environment to analyze the performance and optimize design parameters of the PEM fuel cell system and components. (c) 2005 Published by Elsevier B.V.
引用
收藏
页码:30 / 39
页数:10
相关论文
共 22 条
[1]   PERFORMANCE MODELING OF THE BALLARD-MARK-IV SOLD POLYMER ELECTROLYTE FUEL-CELL .2. EMPIRICAL-MODEL DEVELOPMENT [J].
AMPHLETT, JC ;
BAUMERT, RM ;
MANN, RF ;
PEPPLEY, BA ;
ROBERGE, PR ;
HARRIS, TJ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (01) :9-15
[2]   Dynamic interaction of a proton exchange membrane fuel cell and a lead-acid battery [J].
Amphlett, JC ;
deOliveira, EH ;
Mann, RF ;
Roberge, PR ;
Rodrigues, A ;
Salvador, JP .
JOURNAL OF POWER SOURCES, 1997, 65 (1-2) :173-178
[3]   Modelling static and dynamic behaviour of proton exchange membrane fuel cells on the basis of electro-chemical description [J].
Ceraolo, M ;
Miulli, C ;
Pozio, A .
JOURNAL OF POWER SOURCES, 2003, 113 (01) :131-144
[4]  
EATON BM, 2001, THESIS VIRGINIA TECH
[5]   Experimental analysis of water management in a self-humidifying polymer electrolyte fuel cell stack [J].
Eckl, R ;
Zehtner, W ;
Leu, C ;
Wagner, U .
JOURNAL OF POWER SOURCES, 2004, 138 (1-2) :137-144
[6]  
EVANS JP, 2003, THESIS VIRGINIA TECH
[7]   Analytical and experimental investigations of a proton exchange membrane fuel cell [J].
Ferng, YM ;
Tzang, YC ;
Pei, BS ;
Sun, CC ;
Su, A .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2004, 29 (04) :381-391
[8]   Model-based control of fuel cells: (1) Regulatory control [J].
Golbert, J ;
Lewin, DR .
JOURNAL OF POWER SOURCES, 2004, 135 (1-2) :135-151
[9]  
GURSKI SD, 2003, SAE 2003 WORLD C EXH
[10]   Numerical analysis of a polymer electrolyte fuel cell [J].
Jung, HM ;
Lee, WY ;
Park, JS ;
Kim, CVS .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2004, 29 (09) :945-954