Membrane filtration studies of aquatic humic substances and their metal species: a concise overview. Part 2. Evaluation of conditional stability constants by using ultrafiltration

被引：36

作者：

Nifant'eva, TI ^{[1
]}

Shkinev, VM

Spivakov, BY

Burba, P

机构：

[1] VI Vernadskii Inst Geochem & Analyt Chem, Moscow 117975, Russia

[2] Inst Spectrochem & Appl Spect, D-44139 Dortmund, Germany

来源：

TALANTA | 1999年 / 48卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

humic substances; metal complexes; stability constants; ultrafiltration;

D O I：

10.1016/S0039-9140(98)00249-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The assessment of conditional stability constants of aquatic humic substance (HS) metal complexes is overviewed with special emphasis on the application of ultrafiltration methods. Fundamentals and limitations of stability functions in the case of macromolecular and polydisperse metal-HS species in aquatic environments are critically discussed. The review summarizes the advantages and application of ultrafiltration for metal-HS complexation studies, discusses the comparibility and reliability of st;ability constants. The potential of ultrafiltration procedures for characterizing the lability of metal-HS species is also stressed. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：257 / 267

页数：11

共 75 条

[1]

Aiken G. R., 1985, HUMIC SUBSTANCES SOI

[2]

Alberts J. J., 1983, Aquatic and terrestrial humic materials, P333

[3]

ALLARD J, 1991, HUMIC SUBSTANCES AQU

[4]

[Anonymous], 1993, KST

[5] Determination of metals and their species in aquatic humic substances by using total-reflection X-ray fluorescence spectrometry [J].

Aster, B ;

vonBohlen, A ;

Burba, P .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1997, 52 (07) :1009-1018

[6] STUDY OF INTERACTIONS BETWEEN HEAVY-METALS AND SEWAGE SLUDGES - DETERMINATION OF STABILITY-CONSTANTS AND COMPLEXATION CAPACITIES OF COMPLEXES FORMED WITH CU AND CD [J].

BARON, J ;

LEGRET, M ;

ASTRUC, M .

ENVIRONMENTAL TECHNOLOGY, 1990, 11 (02) :151-162

[7] COMPLEXATION OF ZINC BY NATURAL ORGANIC-LIGANDS IN THE CENTRAL NORTH PACIFIC [J].

BRULAND, KW .

LIMNOLOGY AND OCEANOGRAPHY, 1989, 34 (02) :269-285

[8] EFFECT OF PHYSICOCHEMICAL HETEROGENEITY OF NATURAL COMPLEXANTS .2. BUFFERING ACTION AND ROLE OF THEIR BACKGROUND SITES [J].

BUFFLE, J ;

ALTMANN, RS ;

FILELLA, M .

ANALYTICA CHIMICA ACTA, 1990, 232 (01) :225-237

[9] MEASUREMENT OF COMPLEXATION PROPERTIES OF HUMIC AND FULVIC ACIDS IN NATURAL-WATERS WITH LEAD AND COPPER ION-SELECTIVE ELECTRODES [J].

BUFFLE, J ;

GRETER, FL ;

HAERDI, W .

ANALYTICAL CHEMISTRY, 1977, 49 (02) :216-222

[10] STUDY OF THE COMPLEX-FORMATION OF COPPER(II) BY HUMIC AND FULVIC SUBSTANCES [J].

BUFFLE, J ;

DELADOEY, P ;

GRETER, FL ;

HAERDI, W .

ANALYTICA CHIMICA ACTA, 1980, 116 (02) :255-274

← 1 2 3 4 5 6 7 8 →