Ultraviolet upconversion emissions of Gd3+

被引:100
作者
Cao, Chunyan [1 ,2 ]
Qin, Weiping [1 ]
Zhang, Jisen [2 ]
Wang, Yan [2 ]
Zhu, Peifen [1 ]
Wei, Guodong [1 ]
Wang, Guofeng [1 ]
Kim, Ryongjin [1 ]
Wang, Lili [1 ]
机构
[1] Jilin Univ, State Key Lab Integrated Optoelect, Coll Elect Sci & Engn, Changchun 130012, Peoples R China
[2] Chinese Acad Sci, Key Lab Excited State Proc, Changchun Inst Opt Fine Mech & Phys, Changchun 130033, Peoples R China
关键词
D O I
10.1364/OL.33.000857
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Under 980 nm excitation, upconversion (UC) emissions in the U-V range of 270-320 nm were observed in nanocrystals Y0.795-xGdxYb0.2Tm0.005F3 (x=0, 0.1, 0.2, 0.5, and 0.795), which were synthesized through a hydrothermal method. These UC emissions can be assigned to the transitions of I-6(J), P-6(J) -> S-8(7/2) (Gd3+), and P-3(0)/I-1(6) -> H-3(6) (Tm3+). The energy transfer from Tm3+ to Gd3+ plays a crucial role in populating the excited states of Gd3+. The shortest wavelength of upconverted emission converted from the infrared region was demonstrated here. (C) 2008 Optical Society of America.
引用
收藏
页码:857 / 859
页数:3
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