Structural phase transition accompanied by metal-insulator transition in PrRU4P12

被引:86
作者
Lee, CH
Matsuhata, H
Yamamoto, A
Ohta, T
Takazawa, H
Ueno, K
Sekine, C
Shirotani, I
Lee, CH
机构
[1] Electrotech Lab, Tsukuba, Ibaraki 3058568, Japan
[2] Muroran Inst Technol, Muroran, Hokkaido 0508585, Japan
[3] JFCC, Atsuta Ku, Nagoya, Aichi 4568587, Japan
关键词
D O I
10.1088/0953-8984/13/2/102
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A structural phase transition has been found using electron diffraction technique in PrRu4P12 accompanied by a metal-insulator (M-I) transition (TMI = 60 K). Weak superlattice spots appeared at (H, K, L) (H + K + L = odd) position at a temperature of T = 12 K and 40 K. Above T = 70 K, the spots completely vanished. The space group of the low-temperature phase is probably Pm (3) over bar. This is the first observation of a symmetry other than Im (3) over bar in skutterudite compounds.
引用
收藏
页码:L45 / L48
页数:4
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