Synthesis and characterization of fullerol derived from C60n- precursors

被引：26

作者：

Chen, Y ^{[1
]}

Cai, RF ^{[1
]}

Chen, SM ^{[1
]}

Huang, ZE ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2001年 / 62卷 / 05期

基金：

中国国家自然科学基金;

关键词：

fullerenes; organic compounds; chemical synthesis; infrared spectroscopy; electronic paramagnetic resonance (EPR);

D O I：

10.1016/S0022-3697(00)00242-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this note, we reported a new synthetic method for the preparation of water-soluble fullerol (60% yield) by the reaction of C-60(n-) lithium salt with the acidified methanol/water solution in the presence of oxygen. The elemental analysis showed an average composition of C60H2(OH)(24) The FAB-MS spectrum displays a base peak for C-60 at 720 (m/z), whereas the product's molecular ion peak was not detected. In contrast to the pure C-60, this material exhibits interesting paramagnetic properties. An unusual temperature dependence for the ESR spectrum is observed over the temperature range 300-450 K. This change is irreversible. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：999 / 1001

页数：3

共 17 条

[1] A new route for the selective synthesis of [6,6]-methanofullerenes. Electrosynthesis of C(61)HCMe(3) and C61HCN [J].

Boulas, PL ;

Zuo, YH ;

Echegoyen, L .

CHEMICAL COMMUNICATIONS, 1996, (13) :1547-1548

[2] A NEW METHOD FOR THE PREPARATION OF FULLERENE ANION SALTS - SYNTHESIS AND CHARACTERIZATION OF KC60(THF) [J].

CHEN, J ;

HUANG, ZE ;

CAI, RF ;

SHAO, QF ;

CHEN, SM ;

YE, HJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (18) :2177-2178

[3] EMPIRICAL CORRELATION OF C-13 NMR CHEMICAL-SHIFT WITH ORIENTATIONAL ORDERING IN SOLID KNC60(THF)(M)(N=1-3) [J].

CHEN, J ;

HUANG, ZE ;

CAI, RF ;

SHAO, QF ;

YE, HJ .

SOLID STATE COMMUNICATIONS, 1995, 95 (04) :233-237

[4] SOLID-STATE MAGNETIC-RESONANCE STUDY OF KC60(THF)(X) [J].

CHEN, J ;

SHAO, QF ;

HUANG, ZE ;

CAI, RF ;

CHEN, SM .

CHEMICAL PHYSICS LETTERS, 1995, 235 (5-6) :570-575

[5] ISOMERICALLY PURE ORGANO[60]FULLERENES FROM C-60(2-) SALT - SYNTHESIS AND CHARACTERIZATION OF 1-BENZYL-2-HYDRO[60]FULLERENE [J].

CHEN, JA ;

CAI, RF ;

HUANG, ZE ;

WU, HM ;

JIANG, SK ;

SHAO, QF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (15) :1553-1554

[6]

Chen Y, 1998, EUR POLYM J, V34, P137

[7]

Chen Y, 1998, EUR POLYM J, V34, P421

[8]

Chen Y, 1998, J POLYM SCI POL PHYS, V36, P2653, DOI 10.1002/(SICI)1099-0488(199810)36:14<2653::AID-POLB18>3.0.CO

[9]

2-A

[10]

Chen Y, 1996, J POLYM SCI POL PHYS, V34, P631, DOI 10.1002/(SICI)1099-0488(199603)34:4<631::AID-POLB3>3.3.CO

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