Asymmetric synthesis. Part 29: Asymmetric hydroformylation of styrene catalyzed by chiral spiro diphosphite-rhodium(I) complexes

被引：54

作者：

Jiang, YZ ^{[1
]}

Xue, S

Li, Z

Deng, JG

Mi, AQ

Chan, ASC

机构：

[1] Acad Sinica, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

[2] Hong Kong Polytech Univ, Hong Kong, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 18期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0957-4166(98)00339-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral diphosphite ligands L-1-L-3 were prepared by the reaction of (1S,5S,6R)-(cis,trans)-spiro[4.4]nonane-1,6-diol with chlorophosphites. These ligands were tested in the rhodium catalyzed hydroformylation of styrene and enantioselectivities up to 69% were achieved. High regioselectivities (97%) to 2-phenylpropanal and high yields (98%) were obtained under mild reaction conditions. The influence of reaction conditions is also discussed. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3185 / 3189

页数：5

共 11 条

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