Phosphazenes with (2-pyridylmethylamino) groups .1. Syntheses and crystal structures of pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene and its copper(II) nitrate, platinum(II) chloride, and cobalt(II) nitrate complexes

被引：32

作者：

Diefenbach, U

Kretschmann, M

Stromburg, B

机构：

[1] Institut Für Anorganische Und Analytische Chemie, Freien Universität Berlin, D-14195 Berlin

来源：

CHEMISCHE BERICHTE-RECUEIL | 1996年 / 129卷 / 12期

关键词：

phosphazenes; (2-pyridylmethylamino) groups; copper complex; cobalt complex; platinum complex;

D O I：

10.1002/cber.19961291227

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the (2-pyridylmethylamino)-substituted cyclotriphosphazene N3P3(OC6H5)(5)(NHCH2(C5H4N)-2) (1) with copper(II) nitrate, platinum(II) chloride, and cobalt(II) nitrate yields the stable complexes [Cu(NO3)(2) .(1)(2)] (1a), [PtCl2 .(1)] (1b), [Co(NO3)(2) .(1)] (1c). The X-ray crystallographic studies of these metal complexes revealed the different coordination behavior of the multifunctional ligand.

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页码：1573 / 1578

页数：6

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