Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives

被引：48

作者：

Bashkatova, NV ^{[1
]}

Korotkova, EI ^{[1
]}

Karbainov, YA ^{[1
]}

Yagovkin, AY ^{[1
]}

Bakibaev, AA ^{[1
]}

机构：

[1] Tomsk Polytech Univ, Tomsk, Russia

来源：

JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS | 2005年 / 37卷 / 05期

关键词：

antioxidant; antipyrine; antipyrine derivatives; quantum-chemical parameters; voltammetry;

D O I：

10.1016/j.jpba.2004.11.046

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Electrochemical, quantum-chemical and antioxidant properties of antipyrine and its derivatives have been investigated in this work. New quantum-chemical parameter such as difference of formation heats of a molecule and its cation radical (Delta Delta H-cat) has been used in order to describe properties of the investigated substances. Electrochemical properties (oxidation, reduction potentials) have been investigated. Correlation between the calculated Delta Delta H-cat and the experimentally obtained oxidation potentials for antipyrine and its derivatives has been found. (c) 2004 Elsevier B.V. All rights reserved.

引用

页码：1143 / 1147

页数：5

共 6 条

[1] ELECTROCHEMICAL AND SPECTROSCOPIC PROPERTIES OF CATION RADICALS .3. REACTION PATHWAYS OF CARBAZOLIUM RADICAL IONS [J].