Protonation and dehydration reactions of the Mn4O4L6 cubane and synthesis and crystal structure of the oxidized cubane [Mn4O4L6]+:: A model for the photosynthetic water oxidizing complex

被引：83

作者：

Ruettinger, WF ^{[1
]}

Ho, DM ^{[1
]}

Dismukes, GC ^{[1
]}

机构：

[1] Princeton Univ, Dept Chem, Hoyt Lab, Princeton, NJ 08544 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 06期

关键词：

D O I：

10.1021/ic981145y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and! atomic structure of [Mn4O4L6](+)(CF3SO3-). 1(+)OTf(-) (L = diphenylphosphinate), is reported. This new model for the photosynthetic water oxidizing complex extends the known [Mn4O4](n+) cubane core type to the Mn-4(III,3IV) oxidation state. Synthesis of this cluster is achieved by one-electron oxidation of Mn4O4L6 (1) by molecular oxygen in a series of steps initiated by the protonation or silylation of one oxide bridge in 1.

引用

页码：1036 / +

页数：3

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