A naphthalimide-calixarene as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-

被引:108
作者
Xu, Zhaochao [2 ]
Kim, Suki [2 ]
Kim, Ha Na [2 ]
Han, Su Jung [3 ]
Lee, Chongmok [3 ]
Kim, Jong Seung [4 ]
Qian, Xuhong [1 ]
Yoon, Juyoung [2 ]
机构
[1] E China Univ Sci & Technol, Shanghai Key Lab Chem Biol, Shanghai 200237, Peoples R China
[2] Ewha Womans Univ, Div Nano Sci, Seoul 120750, South Korea
[3] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea
[4] Korea Univ, Dept Chem, Seoul 136701, South Korea
关键词
D O I
10.1016/j.tetlet.2007.10.109
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new naphthalimide-calix[4]arene was synthesized as a two-faced and highly selective fluorescent chemosensor for Cu2+ or F-. This chemosensor displayed a selective fluorescence quenching effect only with Cu2+ among the various metal ions. On the other hand, among the various anions, the title chemosensor displayed a selective fluorescence quenching effect only with F-. The binding mode with F- was further investigated using fluorescence changes and H-1 NMR experiments. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:9151 / 9154
页数:4
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