Heterogeneously catalysed cleavage of carbon-carbon double bonds with hydrogen peroxide using calcined heteropolyacids on oxide supports

被引：27

作者：

Brooks, CD ^{[1
]}

Huang, LC ^{[1
]}

McCarron, M ^{[1
]}

Johnstone, RAW ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 3BX, Merseyside, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 01期

关键词：

D O I：

10.1039/a805831h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of an alkene with aqueous hydrogen peroxide and a catalytic quantity of a heteropolyacid adsorbed onto magnesium, aluminium or zinc oxide leads to complete, rapid cleavage of the alkene to give carbonyl compounds.

引用

页码：37 / 38

页数：2

共 11 条

[1] OXIDATION OF CYCLOPENTENE WITH HYDROGEN-PEROXIDE CATALYZED BY 12-HETEROPOLY ACIDS [J].

FURUKAWA, H ;

NAKAMURA, T ;

INAGAKI, H ;

NISHIKAWA, E ;

IMAI, C ;

MISONO, M .

CHEMISTRY LETTERS, 1988, (05) :877-880

[2]

HENRY PM, 1977, CHEM FUNCTIONAL 1 SA, P965

[3]

HUDLICKY M, 1990, ACS MONOGR SER, P77

[4] HYDROGEN-PEROXIDE OXIDATION CATALYZED BY HETEROPOLY ACIDS COMBINED WITH CETYLPYRIDINIUM CHLORIDE - EPOXIDATION OF OLEFINS AND ALLYLIC ALCOHOLS, KETONIZATION OF ALCOHOLS AND DIOLS, AND OXIDATIVE CLEAVAGE OF 1,2-DIOLS AND OLEFINS [J].

ISHII, Y ;

YAMAWAKI, K ;

URA, T ;

YAMADA, H ;

YOSHIDA, T ;

OGAWA, M .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15) :3587-3593

[5]

IZUMI Y, 1992, ZEOLITE CLAY HETEROP, P163

[6]

MARCH J, 1992, ADV ORG CHEM, P1177

[7] CATALYSIS BY HETEROPOLY COMPOUNDS .3. THE STRUCTURE AND PROPERTIES OF 12-HETEROPOLYACIDS OF MOLYBDENUM AND TUNGSTEN (H3PMO12-XWXO40) AND THEIR SALTS PERTINENT TO HETEROGENEOUS CATALYSIS [J].

MISONO, M ;

MIZUNO, N ;

KATAMURA, K ;

KASAI, A ;

KONISHI, Y ;

SAKATA, K ;

OKUHARA, T ;

YONEDA, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (02) :400-406

[8]

SCHAEFFER JR, 1963, ORG SYNTH, V4, P9

[9] HETEROPOLYANIONS AS OXIDATION CATALYSTS IN A 2-PHASE SYSTEM [J].

SCHWEGLER, M ;

FLOOR, M ;

VANBEKKUM, H .

TETRAHEDRON LETTERS, 1988, 29 (07) :823-826

[10] REACTIONS OF HYDROGEN PEROXIDE .1. A NOVEL USE OF SELENIUM DIOXIDE AS CATALYST FOR OXIDATION OF ACROLEIN TO ACRYLIC ACID [J].

SMITH, CW ;

HOLM, RT .

JOURNAL OF ORGANIC CHEMISTRY, 1957, 22 (07) :746-748

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