Stacking of molecules possessing a fullerene apex and a cup-shaped cavity connected by a silicon connection

被引：104

作者：

Matsuo, Y

Muramatsu, A

Hamasaki, R

Mizoshita, N

Kato, T

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

[2] Univ Tokyo, Dept Chem & Biotechnol, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 02期

关键词：

D O I：

10.1021/ja038816y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexagonal or tetragonal packing of columnar stacks in crystals and liquid crystals has been observed for a series of molecules possessing a fullerene apex and an aromatic cone that are connected with a Si-C connection. The columnar stacking of the new shuttlecock molecules is constitutionally stable but conformationally flexible due to the large cavity created on the top of the fullerene molecule. Copyright © 2004 American Chemical Society.

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页码：432 / 433

页数：2

相关论文

共 20 条

[1] Design, mesomorphic properties, and supramolecular organization of [60]fullerene-containing thermotropic liquid crystals [J].

Chuard, T ;

Deschenaux, R .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :1944-1951

[2] Supramolecular fullerene chemistry [J].

Diederich, F ;

Gómez-López, M .

CHEMICAL SOCIETY REVIEWS, 1999, 28 (05) :263-277

[3] Molecular paneling via coordination [J].

Fujita, M ;

Umemoto, K ;

Yoshizawa, M ;

Fujita, N ;

Kusukawa, T ;

Biradha, K .

CHEMICAL COMMUNICATIONS, 2001, (06) :509-518

[4] Self-assembly of phase-segregated liquid crystal structures [J].

Kato, T .

SCIENCE, 2002, 295 (5564) :2414-2418

[5] NOVEL COLUMNAR LIQUID-CRYSTALS DESIGNED FROM CONE-SHAPED CALIX[4]ARENES - THE RIGID BOWL IS ESSENTIAL FOR THE FORMATION OF THE LIQUID-CRYSTAL PHASE [J].

KOMORI, T ;

SHINKAI, S .

CHEMISTRY LETTERS, 1993, (08) :1455-1458

[6] Self-assembly of discrete cyclic nanostructures mediated by transition metals [J].

Leininger, S ;

Olenyuk, B ;

Stang, PJ .

CHEMICAL REVIEWS, 2000, 100 (03) :853-907

[7] SILYLMETHYLATIONS OF C-60 WITH GRIGNARD-REAGENTS - SELECTIVE SYNTHESIS OF HC60CH2SIME2Y AND C60(CH2SIME2Y)2 WITH SELECTION OF SOLVENTS [J].

NAGASHIMA, H ;

TERASAKI, H ;

KIMURA, E ;

NAKAJIMA, K ;

ITOH, K .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (06) :1246-1248

[8] Chemistry of η5-fullerene metal complexes [J].

Nakamura, E ;

Sawamura, M .

PURE AND APPLIED CHEMISTRY, 2001, 73 (02) :355-359

[9] Functionalized fullerenes in water. The first 10 years of their chemistry, biology, and nanoscience [J].

Nakamura, E ;

Isobe, H .

ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (11) :807-815

[10]

Sauvage J.-P.V., 2001, Molecular machines motors