An extensive class of solids full of holes large enough to enclose over 200 molecules of H2O

被引：9

作者：

Abrahams, Brendan F. ^{[1
]}

FitzGerald, Nicholas J. ^{[1
]}

Robson, Richard ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 45期

关键词：

crystal engineering; macrocycles; metallacycles; ligands; supramolecular chemistry;

D O I：

10.1002/anie.200702656

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Swiss cheese, Gromit! A new class of solids of widely variable composition has essentially the same crystal structure reminiscent of Emmental cheese (see picture). The presence of the roughly spherical holes in the structure, which are large enough to enclose around 200 water molecules, is a consequence of the edge-to-face agglomeration of 12 fluorene units into pseudospherical clusters. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8640 / 8643

页数：4

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2-D

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