A bridging coordination mode of urea and carbamate at a dinuclear nickel(II) centre

被引：60

作者：

Meyer, F ^{[1
]}

Pritzkow, H ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 15期

关键词：

D O I：

10.1039/a802554a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Starting from an active O2H3-bridged bimetallic complex, a bridging coordination mode of both urea and carbamate-the substrate and its first hydrolytic product in urease activity-at a dinickel(II) centre relevant to the active site of the metalloenzyme has been characterised structurally.

引用

页码：1555 / 1556

页数：2

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